WXG-4型旋光仪三分视场亮暗调节

针对WXG-4型旋光仪的均匀亮视场和均匀暗视场的亮度对比不明显问题进行了研究,分析了三分视场光强与起偏器透振方向的关系,得出原因是起偏器透振方向与半波片的光轴夹角太大.旋转起偏器,使其透振方向与半波片的光轴夹角减小并固定,均匀亮视场和均匀暗视场的亮度对比明显,使仪器恢复正常使用.     

氮吸附法测定纳米粒子的比表面积实验

在纳米粒子的性能表征中,比表面积是一个非常重要的参数。本文研究了用氮吸附法测定纳米粒子比表面积的实验方法。     

Determination of the ~(12)C(p, γ)~(13)N reaction rates fromthe ~(12)C(~7Li,~6He)~(13)N reaction

The angular distribution of the 12C(7Li,6He)13N reaction at E(7Li) = 44.0 MeV was measured at the HI-13 tandem accelerator of Beijing, China. The asymptotic normalization coefficient (ANC) of 13N → 12C + p was derived to be (1.64 ± 0.11) fm-1/2 through the distorted wave Born approximation (DWBA) analysis. The ANC was then used to deduce the astrophysical S (E) factors and reaction rates for the 12C(p,γ)13N direct capture reaction at energies of astrophysical relevance.     

Neutron Spectroscopic Factors of ^7Li and Astrophysical ^6Li（n,γ）^7Li Reaction Rates

Angular distributions of the ^7Li（^6Li, ^6Li）^7Li elastic scattering and the ^7Li（^6Li, ^7Lig.s.）^6Li, ^7Li（^6Li, ^7Li0.48）^6Li transfer reactions at Ec.m. = 23.7 MeV are measured with the Q3D magnetic spectrograph. The optical potential of ^6Li ＋ ^7Li is obtained by fitting the elastic scattering differential cross sections. Based on the distorted wave Born approximation （DWBA） analysis, spectroscopic factors of ^7Li =^6Li n are determined to be 0.73 ± 0.05 and 0.90 ± 0.09 for the ground and first exited states in ^7Li, respectively. Using the spectroscopic factors, the cross sections of the ^6 Li（n, γ0,1）^7 Li direct neutron capture reactions and the astrophysical ^6Li（n, γ）^7 Li reaction rates are derived.     

近似逼近l_1精确罚函数的罚函数

本文对可微非线性规划问题提出了一类新的近似渐近算法与一类渐近算法,它们都是基于一类逼近l1精确罚函数的罚函数而提出的.并证明了近似算法所得序列若有聚点则其为原问题的最优解;若所得序列为无界的,则给出了序列值收敛到最优值的一个充分条件.对渐近算法,在弱的假设条件下,证明了算法所得的极小点列有界,且其聚点均为原问题的最优解.并在Mangasarian-Fromovitz约束条件下,证明了有限次迭代之后,所有迭代均为可行的,即迭代所得的极小点为可行点.     

分析化学教学中培养学生学习兴趣的几点探讨

结合以往的教学实践,针对学生学习分析化学课程中存在的一些问题,就如何培养医学检验和卫生检验专业学生的学习分析化学兴趣,进行了几点简要的探讨.     

Microstructure of epitaxial superconductive YBa2Cu3O7 thin films prepared at different deposition rates

A study is reported on the growth mechanism of YBa₂Cu₃O₇ with different growth speeds by high resolution transmission microscopy (HRTEM) and analysis of the interface and thin film microstructure. Two thin films were synthesized by pulse laser deposition on [100], miscut 5°, SrTiO₃ substrate at 820 °C, one with a pulse laser frequency of 1 Hz and one with 6 Hz. Cross-sections were studied by an H-9000 NAR HRTEM along the [010] direction. The growth process of the sample made at 1 Hz was as follows. First, distorted step flow growth occurred on a step-mediated substrate surface of 3–4 cells thickness. Second, about a 15 nm thickness of island shape growth becomes superimposed on the area of the step flow layer. Finally, thin film growth occurred but with growth fluctuation. The sample made at 6 Hz showed the characteristics of island growth; the growth area of island or ball shape was of small size and dense distribution, and seemed to be a confused mosaic stack. The influence of growth speed on YBCO epitaxial film microstructure was studied explicitly by HRTEM.     

钒钨酸盐-CdS纳米粒子复合膜的制备与电致变色性能

通过层-层自组装方法制备了由Dawson结构三钒取代型钨酸盐1-K₉P₂W₁₅V₃O₆₂·18H₂O(P₂W₁₅V₃)与CdS纳米粒子构筑的复合膜材料, 研究了CdS纳米粒子添加和复合膜层数对P₂W₁₅V₃多酸复合膜材料电致变色性能的影响. 采用UV, XRD, SEM和循环伏安等测试手段对复合材料的结构和性能进行了表征; 将电化学工作站和紫外-可见吸收光谱联用, 在-1.0~+1.0 V的电压范围内, 对不同层数、 有无CdS纳米粒子复合的的膜材料的电致变色性能进行研究. 研究结果表明, 20层的复合膜材料性能最佳, 光反差为38.05%, 着色时间为3.57 s, 褪色时间为6.94 s, 最大着色效率达到94.04 cm²/C, 实现了从无色、 蓝色到蓝紫色, 再到无色的可逆颜色变化, 相对于单独P₂W₁₅V₃膜, 光反差提高46.07%, 着色效率提高96.53%, 电致变色性能显著提高.     

焊缝超声相控阵检测数据深度学习降噪方法

超声相控阵检测技术在焊缝检测中具有广泛的应用.超声相控阵检测技术检测信号中常混入噪声导致检测成像时难以分辨真实的缺陷特征.这些噪声主要为无关的反射信号和局部相关的结构噪声,传统的超声图像降噪方法难以有效滤除这些噪声,且存在计算效率低、参数优化复杂等问题.该文提出了一种基于深度学习的焊缝超声相控阵检测技术检测S扫图像的降...     

泡沫铜基底原位生长的铜基导电金属有机框架作为双功能电催化剂

以泡沫铜为基底生长氢氧化铜纳米线,通过原位转化合成二维导电金属有机框架(MOF)材料Cu_3HITP_2(HITP=2,3,6,7,10,11-六氨基三亚苯)作为双功能催化剂,可直接用作析氧及氧还原反应的工作电极,而无需使用额外的基底或粘合剂,且无需后续热处理。研究发现以氢氧化铜纳米线为模板的Cu_3HITP_2表现出了更大的电化学比表面积,这种新型的电极可在碱性溶液(0.1和1.0 mol·L~(-1) KOH)中可以稳定运行,析氧反应中在电流密度达到10 mA·cm~(-2)时的过电位仅为1.53 V,超越了商业二氧化钌的催化性能。此外,该催化剂在氧还原反应中的半波电位达到0.75 V,优于大多数MOF材料。